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Despite decades of progress in reducing nitrogen oxide (NO_x) emissions, ammonium nitrate (AN) remains the primary inorganic component of particulate matter (PM) in Los Angeles (LA). Using aerosol mass spectrometry over multiple years in LA illustrates the controlling dynamics of AN and their evolution over the past decades. These data suggest that much of the nitric acid (HNO₃) production required to produce AN in LA occurs during the nighttime via heterogeneous hydrolysis of N₂O₅. Further, we show that US Environmental Protection Agency–codified techniques for measuring total PM_2.5fail to quantify the AN component, while low-cost optical sensors demonstrate good agreement. While previous studies suggest that declining NO_xhas reduced AN, we show that HNO₃formation is still substantial and leads to the formation of many tens of micrograms per cubic meter of AN aerosol. Continued focus on reductions in NO_xwill help meet the PM_2.5standards in the LA basin and many other regions. 

Exposure to ambient fine particulate matter (PM2.5) is associated with millions of premature deaths annually. Oxidative stress through overproduction of reactive oxygen species (ROS) is a possible mechanism for PM2.5-induced health effects. Organic aerosol (OA) is a dominant component of PM2.5 worldwide, yet its role in PM2.5 toxicity is poorly understood due to its chemical complexity. Here, through integrated cellular ROS measurements and detailed multi-instrument chemical characterization of PM in urban southeastern United States, we show that oxygenated OA (OOA), especially more-oxidized OOA, is the main OA type associated with cellular ROS production. We further reveal that highly unsaturated species containing carbon–oxygen double bonds and aromatic rings in OOA are major contributors to cellular ROS production. These results highlight the key chemical features of ambient OA driving its toxicity. As more-oxidized OOA is ubiquitous and abundant in the atmosphere, this emphasizes the need to understand its sources and chemical processing when formulating effective strategies to mitigate PM2.5 health impacts.